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Trapping Reactive Intermediates by Mechanochemistry : Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents


Štrukil, Vjekoslav; Gracin, Davor; Magdysyuk, Oxana V.; Dinnebier, Robert E.; Friščić, Tomislav
Trapping Reactive Intermediates by Mechanochemistry : Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents // Angewandte Chemie. International edition, 54 (2015), 29; 8440-8443. doi:10.1002/anie.201502026 (članak, znanstveni)


Naslov
Trapping Reactive Intermediates by Mechanochemistry : Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents

Autori
Štrukil, Vjekoslav ; Gracin, Davor ; Magdysyuk, Oxana V. ; Dinnebier, Robert E. ; Friščić, Tomislav

Izvornik
Angewandte Chemie. International edition (1433-7851) 54 (2015), 29; 8440-8443

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Mechanochemistry; reactive intermediates; thiocarbamoylation; thiourea

Sažetak
Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.

Izvorni jezik
Engleski

Indeksirano u
Current Contents , Web of Science Core Collection

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